We are used to counting "base 10". This means that we use powers of 10 to represent successive digits in numbers. We have a units column, a tens column, a hundreds column, a thousands column and so on. We know that 123 is a hundred plus two tens and three units.
The digital circuits that we are using represent a value as patterns of bits. Because each bit can only have two values, 0 or 1 (unlike decimal where each digit can have the ten values 0 - 9) we say that digital circuits work to base two (or binary).
The table shows eight bits, numbered from 7 to 0. Bit 0 is the least significant bit (LSB) and bit 7 is the most significant bit (LSB). As in decimal numbers, the least significant digit is given at the right hand edge of the number.
Each bit in a binary number represents a power of two. I can represent a value, up to the capacity of the number of bits I've got, as a particular pattern of bits:
10110101
- would convert to decimal as (1128) + (064) + (132) + (116) + (08) + (14) + (02) + (11) - giving a total of 181 decimal.
Hexadecimal is counting to base 16. Each digit has 16 possible states, from 0 - 9 and A-F. The value 10 in hex is decimal 16. Having a number base which is a power of two is very useful, because each digit is represented by several bits. If I want to convert a long binary number into hex I simply break the number into sequences of four bits and then convert each four bit item into the corresponding hex digit:
10101101011011101101 1010 1101 0110 1110 1101 0xA 0xD 0x6 0xE 0xD
| 
         Bit Number  | 
      
         Power of 2  | 
      
         HEX value  | 
    
| 
         7  | 
      
         128  | 
      
         0x80  | 
    
| 
         6  | 
      
         64  | 
      
         0x40  | 
    
| 
         5  | 
      
         32  | 
      
         0x20  | 
    
| 
         4  | 
      
         16  | 
      
         0x10  | 
    
| 
         3  | 
      
         8  | 
      
         0x08  | 
    
| 
         2  | 
      
         4  | 
      
         0x04  | 
    
| 
         1  | 
      
         2  | 
      
         0x02  | 
    
| 
         0  | 
      
         1  | 
      
         0x01  |